However, the quasi-Favorskii rearrangement may be achieved through a sequential pathway involving at first the 1,2-addition of an appropriate nucleophilic species on the carbonyl group, followed by treatment with a base leading, through migration of an alkyl group, to the formation of an aldehyde or keto group (Scheme 16) (the nucleophilic species can be either a hydride (Equations (34) and (36)) or an organometallic reagent (Equation (35)).
Table of contents : 组合 1 01 02 03 001 1 2 3 4 5 6 7 8 9组合 2 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30组合 3 31-curtius-rearrangement-2020 32 33-dessmartin-oxidation-2020 34-diazotization-diazonium-salt-2020 35-diazotization-diazonium-salt-2020 (1) 36-dimethane-rearrangement-2020 37-favorskii-rearrangement-2020 38-fischer-indole-synthesis-2020 39-friedelcrafts-acylation--alkylation-2020 40-gabriel-synthesis-2020 41-gewald-reaction-2020 42-glasereglintonhay-coupling-2020 43-grignard-reaction-2020 44-grob-fragmentation-2020 45-haloform-reaction-2020 46-heck-cross-coupling-2020 47-hellvolhardzelinsky-reaction-2020 48-hiyama-cross-coupling-2020 49-hofmann-elimination-2020 50-hornerwadsworthemmons-olefination-2020 51-jones-oxidation-2020 52-kucherov-reaction-2020 53-kumada-cross-coupling-2020 54-leygriffith-oxidation-2020 55-liebeskindsrogl-cross-coupling-2020 56-mannich-reaction-2020 57-mcmurry-coupling-2020 58-meerweinponndorfverley-reduction-2020 59-michael-addition-2020组合 4 60-minisci-reaction-2020 61-mitsunobu-reaction-2020 62-miyaura-borylation-2020 63-mukaiyama-redox-hydration-2020 64-nazarov-cyclization-2020 65-nef-reaction-2020 66-negishi-cross-coupling-2020 67-norrish-type-i--ii-reaction-2020 68-olefin-alkene-metathesis-2020 69-oppenauer-oxidation-2020 70-ozonolysis-2020 71-paalknorr-syntheses-2020 72-paternbchi-reaction-2020 73-pausonkhand-reaction-2020 74-peptide-amide-coupling-2020 75-pictetspengler-reaction-2020 76-pinacolpinacolone-rearrangement-2020 77-polonovski-reaction-2020 78-prilezhaev-epoxidation-2020 79-prins-reaction-2020 80-pummerer-rearrangement-2020组合 5 81-rambergbcklund-rearrangement-2020 82-reformatsky-reaction-2020 83-robinson-annulation-2020 84-shapiro-reaction-2020 85-sonogashira-cross-coupling-2020 86-staudinger-reaction-2020 87-steglich-esterification-2020 88-stille-cross-coupling-2020 89-suzuki-cross-coupling-2020 90-swern-oxidation-2020 91-ugi-reaction-2020 92-ullmann-arylaryl-coupling-2020 93-upjohn-dihydroxylation-2020 94-vilsmeierhaack-reaction-2020 95-wacker-oxidation-2020 96-wagnermeerwein-rearrangement-2020 97-weinreb-ketone-synthesis-2020 98-wittig-reaction-2020 99-wohlziegler-reaction-2020 100-wolffkishner-reduction-2020 101 102
Quasi Favorskii Rearrangement Pdf Download
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